VOC Emissions
Volatile organic compounds (VOC) - Organic compounds whose vapor pressure at 20 °C exceeds 0.13
kPa are referred to as Volatile Organic Compounds. VOC have
been implicated as a major precursor in case of production of
photochemical smog, which causes atmospheric haze, eye
irritation and respiratory problems. Some VOC's are
cancerogenic. VOC emissions are typical for oil processing,
petrochemical and chemical plants.
There are two main types of VOC emissions:
Emissions from storage tanks
Emissions from storage tanks can be either measured (for fixed
roof tanks) or can be calculated (for all tank types) by means
of the U.S. EPA AP-42 method.
The calculation is based on
Tank Emissions Monitoring System TEMS
TEMS allows to obtain emission database and create an emission
report easily and rapidly even for large tank farms. TEMS helps
the user to be in compliance with ever more stringent
legislation requirements on emission recordkeeping and
reporting.
Software TEMS based on EPA's AP-42 equations was developed for
tanks emissions calculations. The program uses metric units of
data entered. The tank construction data, liquid data and
meteorological data are in most cases permanent. Annual number
of turnovers of the stored liquid changes often and must be
regularly updated by. The best way of updating turnovers is the
linking of TEMS to a process information system containing data
about tank levels.
Fugitive emissions data
Sources of fugitive emissions are leaking components of process
equipment such as flanges, valve stem packings, pump and
compressor sealings, etc. Total emission rate from these
sources depens especially on the age of the equipment and on
maintenance routine in the plant.
LDAR Program (Leak Detection And Repair)
All the accessible equipment is monitored by means of the EPA's
reference method 21. Leaking components are tightened (the
first attempt to repair) or repaired during the next shutdown.
The correlations between measured VOC concentration near the
source and the real emission rate developed by EPA allows to
evaluate total emission rate (production losses) due to leaking
component and achievable savings due to repairs of leaking
components.
LDAR Program
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